Halloran, P.R., Booth, B.B.B., Jones, C.D., Lambert, F.H., McNeall, D.J., Totterdell, I.J., Völker, C. (2014)
The mechanisms of North Atlantic CO2 uptake in a large Earth System Model ensemble

Biogeosciences Discussions 11, 14551–14585. doi:10.5194/bgd-11-14551-2014


The oceans currently take up around a quarter of the carbon dioxide (CO2) emitted by human activity. While stored in the ocean, this CO2 is not influencing Earth's radiation budget; the ocean CO2 sink therefore plays an important role in mitigating global warming. CO2 uptake by the oceans is heterogeneous, with the subpolar North Atlantic being the strongest CO2 sink region. Observations over the last two decades have indicated that CO2 uptake by the subpolar North Atlantic sink can vary rapidly. Given the importance of this sink and its apparent variability, it is critical that we understand the mechanisms behind its operation. Here we explore subpolar North Atlantic CO2 uptake across a large ensemble of Earth System Model simulations, and find that models show a peak in sink strength around the middle of the century after which CO2 uptake begins to decline. We identify different drivers of change on interannual and multidecadal timescales. Short-term variability appears to be driven by fluctuations in regional seawater temperature and alkalinity, whereas the longer-term evolution throughout the coming century is largely occurring through a counterintuitive response to rising atmospheric CO2 concentrations. At high atmospheric CO2 concentrations the contrasting Ravelle factors between the subtropical and subpolar gyres, combined with the transport of surface waters from the subtropical to subpolar gyre, means that the subpolar CO2 uptake capacity is largely satisfied from its southern boundary rather than through air–sea CO2 flux. Our findings indicate that: (i) we can explain the mechanisms of subpolar North Atlantic CO2 uptake variability across a broad range of Earth System Models, (ii) a focus on understanding the mechanisms behind contemporary variability may not directly tell us about how the sink will change in the future, (iii) to identify long-term change in the North Atlantic CO2 sink we should focus observational resources on monitoring subtropical as well as the subpolar seawater CO2, (iv) recent observations of a weakening subpolar North Atlantic CO2 sink suggests that the sink strength is already in long-term decline.

Received: 15 Sep 2014 – Accepted: 25 Sep 2014 – Published: 13 Oct 2014